High-resolution historical records from Pettaquamscutt River basin sediments: 1. Pb and varve chronologies validate record of Cs released by the Chernobyl accident     

Ana Lúcia Lima  J. Bradford Hubeny  John W. King  Timothy I. Eglinton 《Geochimica et cosmochimica acta》2005,69(7):1803-1812

Cesium-137 derived from the explosion of the Chernobyl reactor in 1986 was preserved in anoxic sediments from a coastal environment in southern Rhode Island. Although the radioactive plume was detected in surface air samples at several locations in the United States, this is the first known record of a Chernobyl ¹³⁷Cs peak in sediments from North America. The inventory of Chernobyl ¹³⁷Cs that was preserved in the Pettaquamscutt River is small compared to European counterparts and should only be detectable for the next 15-20 yr. However, the presence of two ¹³⁷Cs peaks (1963 and 1987) identifies a well-dated segment of the sediment column that could be exploited in understanding the decomposition and preservation of terrestrial and aquatic organic matter. Different methods for calculating the ²¹⁰Pb chronology were also evaluated in this study and checked against independent varve counting. The end result is a detailed chronology of a site well suited for reconstruction of historical records of environmental change.  相似文献   

Paleohydrology of Andean saline lakes from sedimentological and isotopic records, Northwestern Argentina     

Blas Valero-Garcés  Antonio Delgado-Huertas  Norma Ratto  Ana Navas  Larry Edwards 《Journal of Paleolimnology》2000,24(3):343-359

The paleohydrological evolution of several high altitude, saline lakes located in the southernmost Altiplano (El Peinado and San Francisco basins, Catamarca province, NW Argentina) was reconstructed applying sedimentological, geochemical and isotopic techniques. Several playa lakes from the San Francisco basin (26° 56 S; 68° 08 W, 3800-3900 m a.s.l.) show evidence of a recent raise in the watertable that led to modern deposition of carbonate and diatomaceous muds. A 2 m - long core from El Peinado Lake (26° 29 59 S, 68°05 32 W, 3820 m a.s.l.) consists of calcitic crusts (unit 3), overlaid by an alternation of macrophyte-rich and travertine clast- rich, laminated muds (unit 2), and topped by travertine facies (unit 1). This sedimentary sequence illustrates a paleohydrological evolution from a subaerial exposure (unit 3) to a high lake stand (unit 2), and a subsequent smaller decrease in lake level (unit 1). The ¹³C_{organic matter}record also reflects the lake transgression between units 3 and 2. Although there is a general positive correlation between ¹⁸O_carbonate and salinity proxies (Na, Li and B content), the large data dispersion indicates that other factors besides evaporation effects control chemical and isotopic composition of lakewater. Consequently, the oxygen isotopic composition cannot be interpreted exclusively as an indicator of salinity or evaporation ratio. The degassing of CO₂ during groundwater discharge can explain the enriched ¹³C values for primary carbonates precipitated. The carbon budget in these high altitude, saline lakes seems to be controlled by physical rather than biological processes.The Altiplano saline lakes contain records of environmental and climatic change, although accurate ¹⁴C dating of these lacustrine sediments is hindered by the scarcity of terrestrial organic material, and the large reservoir effects. Sedimentologic evidence, a ²¹⁰Pb-based chronology, and a preliminary U/Th chronology indicate a very large reservoir effect in El Peinado, likely as a result of old groundwaters and large contributions of volcanic and geothermal ¹⁴C-free CO₂ to the lake system. Alternative chronologies are needed to place these paleorecords in a reliable chronological framework. A period of increased water balance in the San Francisco basin ended at about 1660 ± 82 yr B.P. (calendar yr U/Th age), and would correlates with the humid phase between 3000 and 1800 yr B.P detected in other sites of the southern Altiplano. Both, ²¹⁰Pb and preliminary U/Th dating favor a younger age for the paleohydrological changes in El Peinado. The arid period reflected by subaerial exposure and low lake levels in unit 3 would have ended with a large increase in effective moisture during the late 17th century. The increased lake level during deposition of unit 2 would represent the period between AD1650 - 1900, synchronous to the Little Ice Age. This chronological framework is coherent with other regional records that show an abrupt transition from more arid to more humid conditions in the early 17th century, and a change to modern conditions in the late 19th century. Although there are local differences, the Little Ice Age stands as a significant climatic event in the Andean Altiplano.  相似文献   

Optical absorption and electron spin resonance in blue and green natural beryl     

Ana Regina Blak  Sadao Isotani  Shigueo Watanabe 《Physics and Chemistry of Minerals》1982,8(4):161-166

A comparative study of blue and green beryl crystals (from the region of Governador Valadares, Minas Gerais, Brazil) using electron paramagnetic resonance (EPR) and optical absorption (OA) spectroscopy is reported. The EPR spectra show that Fe³⁺ in blue beryl occupies a substitutional Al³⁺ site and in green beryl is localized in the structural channels between two O₆ planes. On the other hand the infrared spectra show that the alkali content in the blue beryl is mostly at substitutional and/or interstitial sites and in green beryl is mostly in the structural channels. The OA spectra show two types of Fe²⁺. Thermal treatments above 200° C in green beryl cause the reduction of Fe³⁺ into Fe²⁺ accompanied by a change of color to blue. The blue beryl color does not change on heating. The kinetics of the thermal conversion of Fe³⁺ into Fe²⁺ is composed of two first order processes; the first one has an activation energy ΔE ₁=0.30 eV and the second one has an activation energy ΔE ₂=0.46 eV.  相似文献   

Sediment disturbance off the Tagus Estuary, Western Portugal: chronic contamination, sewage outfall operation and runoff events     

Silva S  Ré A  Pestana P  Rodrigues A  Quintino V 《Marine pollution bulletin》2004,49(3):154-162

Sediment disturbance patterns in the coastal area off the Tagus Estuary (Portugal) have been assessed using a set of combined techniques. The potential sources of disturbance in the area include chronic contamination of the fine sediments originating from the estuary, a local input from a long-sea sewage outfall and occasional high runoff episodes following torrential rain. The Sediment Quality Triad approach, combining environmental chemistry (namely organic contaminants), macrofaunal benthic communities and laboratory sediment toxicity assays, was performed on sediment samples from 20 sites. The samples were collected before the outfall commenced operation and four years after commissioning, in order to evaluate the relative magnitudes of the three potential sources of disturbance. The sediment contamination created by the estuary was identified as the most important cause of reduced sediment quality, as disturbance in all three components of the Sediment Quality Triad were only found in a site located near the estuary.  相似文献   

Palaeokarst and rauhwacke development,mountain uplift and subaerial sliding of tectonic sheets (northern Sierra de los Filabres,Betic Cordilleras,Spain)     

Orozco  Miguel  Molina  José Miguel  Crespo-Blanc  Ana  Alonso-Chaves  Francisco Manuel 《Geologie en Mijnbouw》1999,78(1):103-117

The rauhwackes near Serón in the northern Sierra de los Filabres (S Spain), previously considered as true tectonic breccias, are reinterpreted on the basis of sedimentological, geomorphological and geometrical evidence as subaerial or nearly subaerial sedimentary deposits. Channel fills, parallel lamination, cross-lamination, graded bedding, sedimentary clastic dykes and other sedimentary structures and features occur in the rauhwacke body. These sedimentary rocks correspond to continental deposits of alluvial and karstic origin deposited over a karstified erosional surface of Nevado–Filabride marbles. Although no fossils have been found in the rauhwackes, a Tortonian age for these rocks is suggested on the basis of structural arguments and lithostratigraphic data from the nearby Almanzora basin. The rauhwackes were buried by slabs of Alpujarride rocks that gravitationally slid over them during the uplifting of the Sierra de los Filabres.  相似文献   

Methodological issues involved in the definition of the marine sector     

Ana Luiza Cortez 《GeoJournal》1988,16(3):247-255

Recently, the debate surrounding the United Nations Convention in the Law of the Sea (UNCLOS) and the Exclusive Economic Zones (EEZ) has been extended to the realm of economic growth and planning. Although coastal states are making efforts to determine what resources they have in their EEZs, little is known about the exact contribution those resources are making or potentially could make to enhanced economic growth. This paper suggests an accounting framework, based on existing literature, which explicity delineates the industries that should be considered a part of the marine sector. Criteria are suggested to help determine exactly where a particular industry falls. Several methodological issues are discussed in detail.The views expressed here are those of the author and do not necessarily represent those of the United Nations.  相似文献   

Genericity of the non-periodic solutions of the central force problem     

Ana Nunes  Josefina Casasayas 《Astrophysics and Space Science》1990,165(1):95-99

We study the classical problem of two-dimensional motion of a particle in the field of a central force proportional to a real power of the distancer. for negative energy and (0, 2), each energy levelI _h is foliated by the invariant toriI _hc of constant angular momentumc and, by Liouville-Arnold's theorem, the flow on eachI _hc is conjugated to a linear flow of rotation number _h (c).A well-known result asserts that if we require _h (c) to be rational for every value ofh andc, the, must be equal to one (Kepler's problem). In this paper we prove that for almost every (0, 2) _h (c) is a non-constant continuous function ofc, for everyh<0. In particular, we deduce that motion under central potentials is generically non-periodic.Partially supported by CIRIT under grant No. EE88/2.  相似文献   

Model of geomagnetic paleosecular variations for the Northern Hemisphere     

Ana M. Sinito  Juan F. Vilas 《Studia Geophysica et Geodaetica》1991,35(4):334-343

Summary A model of radial drifting and oscillating dipoles to represent geomagnetic palaeosecular variations, which showed to be appropriate for the Southern Hemisphere, is evaluated for the Northern Hemisphere. After a new fitting of some involved parameters, its theoretical results are compared with the palaeomagnetic data of Lake de Bouchet (France) and the Black Sea. A time lag between the declination and inclination profiles is observed in both cases. A good cross-correlation coefficient is obtained for the declination and inclination data.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990.  相似文献   

Lateral heterogeneities in the upper and mid-mantle conductivity in Argentina     

Ana Osella  Alicia Favetto  Patricia Martinelli 《Pure and Applied Geophysics》1993,141(1):139-156

Regional studies of Sq variations measured at five permanent observatories in Argentina were performed to estimate the distribution of the electrical conductivity of the upper and mid-mantle, reaching a depth of approximately 800 km. After separating the total field into its parts of external and internal origin, the in duced field was modeled, applying two-dimensional techniques. Additionally, induction arrows and an equivalent apparent resistivity curve were calculated A north-south heterogeneity was detected, showing an increase of the conductivity of the shallower layers north of the profile, which may be related to the presence of high volcanic activity in the area.Also at CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas).  相似文献   

On the variability of seasonal temperature in southern South America     

Ana Laura Berman  Gabriel Silvestri  Rosa Compagnucci 《Climate Dynamics》2013,40(7-8):1863-1878

The aim of this paper is to investigate different aspects of the seasonal-to-interannual temperature variability in Eastern Patagonia, the southernmost area of South America, east of the Andes Cordillera. Homogenous regions of seasonal variability and the atmospheric circulation patterns associated with warm and cold conditions in each of them are described in this study. Relationships between temperature in Eastern Patagonia and that registered in other areas of southern South America are also addressed. Results show that the northern and southern areas of Eastern Patagonia have different temperature variability in summer and autumn whereas the temperature variability tends to be more homogeneous within the region during winter and spring. Warm (cold) conditions in the northern areas are associated with reinforced (weakened) westerlies in summer, winter and spring whereas northerly (southerly) advections of warm (cold) air toward the region produce such conditions in autumn. Temperature in the southern portion of Eastern Patagonia is affected by anticyclonic (cyclonic) anomalies that enhance (reduce) the incoming solar radiation and induce reinforced (weakened) westerlies promoting warm (cold) conditions in the region. Furthermore, cyclonic (anticyclonic) anomalies at subpolar latitudes hinder (favor) outbreaks of cold air increasing (decreasing) the temperature over areas of Eastern Patagonia. The circulation anomalies associated with warm (cold) conditions in Eastern Patagonia also promote cold (warm) conditions over areas of northern Argentina, Paraguay and southern Brazil. Consequently, a dipole of temperature is detected in southern South America with centers of opposite sign over these regions.  相似文献